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Modification of wetting property of Inconel 718 surface by nanosecond laser texturing

机译:纳秒激光纹理化对Inconel 718表面润湿性的改性

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摘要

Topographic and wetting properties of Inconel 718 (IN718) surfaces were modified via nanosecond laser treatment. In order to investigate surface wetting behavior without additional post treatment, three kinds of microstructures were created on IN718 surfaces, including line pattern, grid pattern and spot pattern. From the viewpoint of surface morphology, the results show that laser ablated grooves and debris significantly altered the surface topography as well as surface roughness compared with the non-treated surfaces. The effect of laser parameters (such as laser scanning speed and laser average power) on surface features was also discussed. We have observed the treated surface of IN718 showed very high hydrophilicity just after laser treatment under ambient air condistion.And this hydrophicility property has changed rapidly to the other extreme; very high hydrophobicity over just about 20 days. Further experiments and analyses have been carried out in order to investigate this phenomena. Based on the XPS analysis, the results indicate that the change of wetting property from hydrophilic to hydrophobic over time is due to the surface chemistry modifications, especially carbon content. After the contact angles reached steady state, the maximum water contact angle (WCA) for line-patterned and grid-patterned surfaces increased to 152.3 1.2° and 156.8 1.1° with the corresponding rolling angle (RA) of 8.8 1.1° and 6.5 0.8°, respectively. These treated IN718 surfaces exhibited superhydrophobic property. However, the maximum WCA for the spot-patterned surfaces just increased to 140.8 2.8° with RA above 10°. Therefore, it is deduced that laser-inscribed modification of surface wettability has high sensitivity to surface morphology and surface chemical compositions. This work can be utilized to optimize the laser processing parameters so as to fabricate desired IN718 surfaces with hydrophobic or even superhydrophobic property and thus extend the applications of IN718 material in various fields.
机译:Inconel 718(IN718)表面的形貌和润湿性能通过纳秒激光处理进行了修改。为了研究表面润湿行为而无需进行额外的后处理,在IN718表面上创建了三种微结构,包括线型,网格型和斑点型。从表面形态的观点来看,结果表明,与未处理的表面相比,激光烧蚀的沟槽和碎屑显着地改变了表面形貌以及表面粗糙度。还讨论了激光参数(例如激光扫描速度和激光平均功率)对表面特征的影响。我们已经观察到,在环境空气条件下进行激光处理后,IN718的处理过的表面显示出非常高的亲水性。而且这种亲水性已经迅速改变到另一个极端。仅约20天就具有很高的疏水性。为了研究这种现象,进行了进一步的实验和分析。基于XPS分析,结果表明,润湿性从亲水性到疏水性随时间的变化是由于表面化学修饰,尤其是碳含量。接触角达到稳态后,线型和网格型表面的最大水接触角(WCA)增加到152.3 1.2°和156.8 1.1°,相应的滚动角(RA)分别为8.8 1.1°和6.5 0.8° , 分别。这些经处理的IN718表面表现出超疏水性能。但是,当RA高于10°时,点状图案表面的最大WCA仅增加到140.8 2.8°。因此,可以推断出,对表面润湿性进行激光刻印的改性对表面形态和表面化学组成具有很高的敏感性。可以利用这项工作来优化激光加工参数,以制造具有疏水性甚至超疏水性的​​所需IN718表面,从而扩展IN718材料在各个领域的应用。

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